Identification of color centers on MgO(001) thin films with scanning tunneling microscopy

Localized electronic defects on the surface of a 4 monolayer (ML) thin MgO(001) film deposited on Ag(001) have been investigated by low-temperature scanning tunneling microscopy and spectroscopy. Depending on the location of the defect, we observe for the first time different defect energy levels in the band gap of MgO. The charge state of defects can be manipulated by interactions with the scanning tunneling microscope tip. Comparison with ground state energy levels of color centers on the MgO surface obtained from embedded cluster calculations corroborates the assignment of the defects to singly and doubly charged color centers.     

Direct synthesis of a metalloporphyrin complex on a surface

We demonstrate that well-defined monolayers of a metal complex on a surface can be prepared by direct vapor deposition of the metal atoms on monolayers of the ligand. In particular, ordered monolayers of adsorbed tetraphenylporphyrin (2H-TPP) on a silver surface were exposed to cobalt vapors, resulting in the complexation of the metal by the porphyrin. The formation of the metal complexes was monitored by means of X-ray photoelectron spectroscopy (XPS), which reveals that this metalation reaction leads to a chemical equivalence of all four nitrogen atoms. The described in situ metalation provides a convenient way to produce adsorbed monolayers of more reactive (e.g., air- or solvent-sensitive) or thermally unstable metalloporphyrins that are difficult to evaporate or even to obtain as pure compounds at room temperature.     

The bicompletion of the Hausdorff quasi-uniformity

We study conditions under which the Hausdorff quasi-uniformity UH of a quasi-uniform space (X,U) on the set P₀(X) of the nonempty subsets of X is bicomplete.Indeed we present an explicit method to construct the bicompletion of the T₀-quotient of the Hausdorff quasi-uniformity of a quasi-uniform space. It is used to find a characterization of those quasi-uniform T₀-spaces (X,U) for which the Hausdorff quasi-uniformity of their bicompletion on is bicomplete.     

Trace Analysis by Heavy Ion Induced X-Ray Emission

 Various K-, L- and M-shell X-ray production cross sections are measured for heavy ion impact on elements in the range Z ₂ = 13 to 83. The ion species range from Z ₁ = 10 to 36, and ion energies from 1 to 16 MeV are used. Enhanced cross sections are observed when the projectile K- or L- binding energy is similar to the energy of the target K-, L- or M-shell. This effect is used to improve the analysis sensitivity for selected elements. As an example trace analysis of Fe in glass with V, Mn, Co and Ni ions is investigated. Results are compared with proton induced X-ray emission analysis on the same samples. In these samples Fe-K_α X-ray production is similar for irradiation with 3 MeV protons and 14 MeV Ni ions. However the signal to background ratio is four times higher for the irradiation with Ni ions as compared to irradiation with protons. Advantages and drawbacks of heavy ion induced X-ray emission for quantitative analysis compared to proton induced X-ray emission analysis are discussed.     

A law of the iterated logarithm for heavy-tailed random vectors

For a random vector belonging to the (generalized) domain of operator semistable attraction of some nonnormal law we prove various variants of Chover's law of the iterated logarithm for the partial sum. Furthermore we also derive some large deviation results necessary for the proof of our main theorems. Received: 30 September 1998 / Revised version: 28 May 1999     

Strongly τ-Decomposable and Selfdecomposable Laws on Simply Connected Nilpotent Lie Groups

 Let ? be a simply connected nilpotent Lie group with Lie Algebra ? and let τ be a contraction on ?. A probability measure μ on ? is strongly τ-decomposable iff it is representable as the limit of for some probability ν on ?. We show that such a limit exists if and only if ν possesses a finite logarithmic moment with respect to a homogeneous norm on ?. This result is then generalized to the class of selfdecomposable laws on ?. We also show that selfdecomposable laws on ? correspond in a 1–1 way to operator selfdecomposable laws on the tangent space ?. Received 1 October 1998; in revised form 29 March 1999     

2-stannaindenes and 2-stannaindanes

Condensation of o-xylylene bis(triphenylphosphorane) 4 with [(Me₃Si)₂N]₂Sn yields the 1,3-bis(triphen-ylphosphoranediyl)-2σ²-stannaindene 2 , which is orange as a solid and red in solution and which demonstrates stannylene reactivity. Alkyl bromides andiodides add to 2 to give the corresponding 2σ⁴-stannaindanes. In the reaction with PCl₃, the tin atom in 2 is replaced by a phosphenium ring member. A secondary product in the preparation of 2 is the spirocyclic 2σ⁴-stannaindane 12. Its structure has been determined by X-ray analysis. © 1998 John Wiley & Sons, Inc. Heteroatom Chem 9:103–108, 1998     

Structure and Conformation of Individual Molecules upon Adsorption of a Mixture of Benzoporphyrins on Ag(111), Cu(111), and Cu(110) Surfaces

The front cover artwork is provided by the groups of Prof. Dr. Hans-Peter Steinrück and Prof. Dr. Norbert Jux at the Friedrich-Alexander-Universität (FAU) Erlangen-Nürnberg. The image shows a mixture of six 2H-tetrakis-(3, 5-di-tert-butyl-phenyl)(x)benzoporphyrins (2H-diTTBP(x)BPs, x = 0, 1, 2-cis, 2-trans, 3, or 4) molecules forming a porous square structure on Ag(111) as observed in scanning tunneling microscopy (STM) at room temperature. Read the full text of the Research Article at 10.1002/cphc.202300355 .     

Formation and Surface Behavior of Pt and Pd Complexes with Ligand Systems Derived from Nitrile-functionalized Ionic Liquids Studied by XPS

We studied the formation and surface behavior of Pt(II) and Pd(II) complexes with ligand systems derived from two nitrile-functionalized ionic liquids (ILs) in solution using angle-resolved X-ray photoelectron spectroscopy (ARXPS). These ligand systems enabled a high solubility of the metal complexes in IL solution. The complexes were prepared by simple ligand substitution under vacuum conditions in defined excess of the coordinating ILs, [C₃CNC₁Im][Tf₂N] and [C₁CNC₁Pip][Tf₂N], to immediately yield solutions of the final products. The ILs differ in the cationic head group and the chain length of the functionalized substituent. Our XPS measurements on the neat ILs gave insights in the electronic properties of the coordinating substituents revealing differences in donation capability and stability of the complexes. Investigations on the composition of the outermost surface layers using ARXPS revealed no surface affinity of the nitrile-functionalized chains in the neat ILs. Solutions of the formed complexes in the nitrile ILs showed homogeneous distribution of the solute at the surface with the heterocyclic moieties preferentially orientated towards the vacuum, while the metal centers are rather located further away from the IL/vacuum interface.